Organic Solutes in Aqueous Solutions

B46 Fumaric acid Percival, P.W., Roduner, E. and Fischer, H. in Adv. Chem. Ser. 1979, 175, 335; ed. by H.J. Ache, ACS, Washington DC, 1979. Reaction: HOOCC(H) = C(H)COOH + Mu ® HOOCH(Mu)-C(H)COOH Type of reaction: addition across the olefinic bond kM = 1.4 x 1010 dm3mol-1s-1    pH = 1.0 KIE = kM / kH = 1.4 x 1010 / 3.7 x 109 » 4 kH = 3.7 x 109 dm3mol-1s-1 recent data from Vojnarowits at all (to be published)

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Table A - Inorganic Solutes in Aqueous Solutions
Table B - Organic Solutes in Aqueous Solutions
Table C - Solutes Unreactive Towards Muonium Atoms in Aqueous Solutions
Table D - Inorganic and Organic Solutes in Nonaqueous Solutions
Table E - Early Muonium Rate Constants
Table F - (P_M) and (P_D) fractions

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