B54
Barnabas,
M.V. and Walker, D.C.
Can.
J. Chem., 1991,
69, 1252.
Reaction:
CH3SCH2CH2C(H)(NH2)
–COOH + Mu ®
MuH + ?
Type
of reaction: H – atom abstraction
kM
= 1.4 x 107 dm3mol-1s-1
KIE = kM
/ kH = 1.4 x 107 / 3.5 x 108 = 0.04
kH
= 3.5 x 108 dm3mol-1s-1 at pH =
1.0 ie for conjugated acid
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm
Muonium reactions in the micellar systems
kM = 1.4 x 107 dm3mol-1s-1
in the SDDS micelles
from: Barnabas, M.V. and Walker, D.C., Can. J. Chem.
1999, 69, 1252.
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