B56
Stadlbauer,
J.M. , Ng, B.W., Walker, D.C.,
Jean, Y.C. and Ito, Y.
Can.
J. Chem., 1981, 59,
3261.
Reaction:
H2C=C(CH3)COOCH3 + Mu ®
Mu CH2C(CH3)COOCH3
Type
of reaction: addition across the olefinic bond
kM
= (9.5 ±
1.9) x 109 dm3mol-1s-1
KIE = kM
/ kH = 9.5 x 109 / 7.2 x 108 = 13
kH
= 7.2 x 108 dm3mol-1s-1 from:
www.rcdc.nd.edu/compilations/HAtom/H.htm