Organic Solutes in Aqueous Solutions

B55

B56

Methylmethacrylate

Stadlbauer, J.M. , Ng, B.W.,  Walker, D.C., Jean, Y.C. and Ito, Y.
Can. J. Chem., 1981, 59, 3261.

Reaction: H2C=C(CH3)COOCH3 + Mu ® Mu CH2C(CH3)COOCH3

Type of reaction: addition across the olefinic bond

kM = (9.5 ± 1.9) x 109 dm3mol-1s-1  

KIE = kM / kH = 9.5 x 109 / 7.2 x 108 = 13

kH = 7.2 x 108 dm3mol-1s-1 from: www.rcdc.nd.edu/compilations/HAtom/H.htm

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