Organic Solutes in Aqueous Solutions

B58

B59

Nitrobenzene

Stadlbauer, J.M., Ng, B.W., Ganti, R. and Walker, D.C.

J. Am. Chem. Soc., 1984, 106, 3151.

Reaction: C6H5NO2 + Mu ® MuC6H5NO2

Type of reaction: addition to benzene ring

kM = 1.1 x 1010 dm3mol-1s-1   

KIE = kM / kH = 1.1 x 1010 / 1.6 x 109 = 7

kH = 1.6 x 109 dm3mol-1s-1  average of two values from: www.rcdc.nd.edu/compilations/HAtom/H.htm

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