Organic Solutes in Aqueous Solutions

B60

B61

4-Nitrobenzoic acid

Stadlbauer, J.M., Miyake, Y., Ng., B.W., Phillips, E.C. and Walker, D.C.
Radiat. Phys. Chem., 1986, 28, 95.

Reaction: p-O2NC6H4COOH + Mu ® p-O2NC6H4(Mu)COOH

Type of reaction: addition of Mu into the benzene ring

kM = 1.25 x 1010 dm3mol-1s-1   

KIE = kM / kH = 1.25 x 1010 / 9.9 x 108 = 12.6

kH = 9.9 x 108 dm3mol-1s-1  average of 2 values

from: www.rcdc.nd.edu/compilations/HAtom/H.htm

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