B64
Stadlbauer,
J.M., Barnabas, M.V. and Walker, D.C.
J.
Phys. Chem.,
1997, 101, 2442.
Reaction:
-OOCCOOH
+ Mu ®
-HOOCC(OMu)OH
Type
of reaction: addition to C=O of carboxylate group with Mu attached to an O
atom
kM(obs)
= 6.8 x 107 dm3mol-1s-1
at pH »
3 (90 % HC2O4-)
kM
= 7.1 x 107 dm3mol-1s-1
value deduced
kH
– unknown at pH »
3