Organic Solutes in Aqueous Solutions

B79

B83

Thioacetamide

Barnabas, M.V., Venkateswaran, K. and Walker, D.C.

Can. J. Chem., 1989, 67, 120.

Reaction: CH3CSNH2 + Mu ® CH3C(Mu)SNH2

Type of reaction: addition to C=S with Mu attached to C atom

kM = 3 x 1010 dm3mol-1s-1   

KIE = kM / kH = 3 x 1010 / 6 x 109 = 5.0

kH = 6 x 109 dm3mol-1s-1   from: www.rcdc.nd.edu/compilations/HAtom/H.htm
 

Muonium reactions in the micellar systems

kM = 3 x 1010 dm3mol-1s-1 in the CTAB micelles

from: Barnabas, M.V. and Walker, D.C., Can. J. Chem. 1999, 69, 1252.


Print Next

Back to the top