Organic Solutes in Aqueous Solutions

B90 Valine Barnabas, M.V. and Walker, D.C. Can. J. Chem., 1991, 69, 1252. Reaction: (CH3)2CH-C(H)(NH2)-C(=O)OH + Mu ® MuH + ? Type of reaction: H abstraction proposed kM = 5 x 106 dm3mol-1s-1    KIE = kM / kH = 5 x 106 / 1.2 x 107 = 0.4 kH = 1.2 x 107 dm3mol-1s-1  pH = 7.0   from: www.rcdc.nd.edu/compilations/HAtom/H.htm   Muonium reactions in the micellar systems kM » 108 dm3mol-1s-1 in the CTAB micelles kM » 5 x 107 dm3mol-1s-1 in the SOS micelles from: Barnabas, M.V. and Walker, D.C., Can. J. Chem. 1999, 69, 1252.

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Table A - Inorganic Solutes in Aqueous Solutions
Table B - Organic Solutes in Aqueous Solutions
Table C - Solutes Unreactive Towards Muonium Atoms in Aqueous Solutions
Table D - Inorganic and Organic Solutes in Nonaqueous Solutions
Table E - Early Muonium Rate Constants
Table F - (P_M) and (P_D) fractions

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