Organic Solutes in Aqueous Solutions

B7

B7

Adenine

Barnabas, M.V. and Walker, D.C.

Can. J. Chem., 1991, 69, 1252.

Reaction: Adenine + Mu ® Mu-adenine adduct

Type of reaction: addition

kMu = 2 x 109 dm3mol-1s-1   

KIE = kM / kH = 2 x 109 / 1 x 108 = 20

kH = 1 x 108 dm3mol-1s-1  pH = 7.0  from: www.rcdc.nd.edu/compilations/HAtom/H.htm

 

Muonium reactions in the micellar systems

kM » 2 x 109 dm3mol-1s-1 in the CTAB micelles

from: Barnabas, M.V. and Walker, D.C., Can. J. Chem. 1999, 69, 1252.

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