Organic Solutes in Aqueous Solutions

B21

B21

2-Bromopropionic acid

Percival, P.W., Roduner, E. and Fischer, H.

in Adv. Chem. Ser. 1979, 175, 335; ed. by H.J. Ache, ACS, Washington DC, 1979.

Reaction: CH3CHBrCOOH + Mu ® MuBr + CH3CHCOOH

Type of reaction: bromine abstraction

kM = 4 x 109 dm3mol-1s-1   at pH = 1.0

KIE = kM / kH = 4 x 109 / 1.4 x 109 = 2.9

kH = 1.4 x 109 dm3mol-1s-1  from: www.rcdc.nd.edu/compilations/HAtom/H.htm

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