B21
Percival,
P.W., Roduner, E. and Fischer, H.
in
Adv. Chem. Ser. 1979, 175, 335; ed. by H.J. Ache, ACS,
Washington DC, 1979.
Reaction:
CH3CHBrCOOH + Mu ®
MuBr + CH3CHCOOH
Type
of reaction: bromine abstraction
kM
= 4 x 109 dm3mol-1s-1
at pH = 1.0
KIE = kM
/ kH = 4 x 109 / 1.4 x 109 = 2.9
kH
= 1.4 x 109 dm3mol-1s-1
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm