Organic Solutes in Aqueous Solutions

B1 Acetaldehyde Stadlbauer, J.M., Venkateswaran, K. and Walker, D.C. Can. J. Chem., 1997, 75, 74. Reaction: CH3CHO + Mu ® CH3CH(OMu)                CH3CHO + Mu ® MuH + CH2 CHO Type of reaction: addition to C = O bond with Mu attached predominantly to O atom and abstraction of H kM = (1.75 ± 0.2) x 108 dm3mol-1s-1    pH = 6 ¸ 7 KIE = kM / kH = 1.75 x 108 / 3.1 x 107 = 5.6 kH = 3.1 x 107 dm3mol-1s-1  from: www.rcdc.nd.edu/compilations/HAtom/H.htm

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Table A - Inorganic Solutes in Aqueous Solutions
Table B - Organic Solutes in Aqueous Solutions
Table C - Solutes Unreactive Towards Muonium Atoms in Aqueous Solutions
Table D - Inorganic and Organic Solutes in Nonaqueous Solutions
Table E - Early Muonium Rate Constants
Table F - (P_M) and (P_D) fractions

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