B34
Percival,
P.W., Roduner, E. and Fischer, H.
in
Adv. Chem. Ser. 1979, 175, 335; ed. by H.J. Ache, ACS,
Washington DC, 1979.
Reaction:
HOOCC(OH)=C(OH)COOH + Mu ®
HOOCMu(OH)-C(OH)COOH
Type
of reaction: addition across the olefinic bond
kM
= 4.5 x 107 dm3mol-1s-1 pH
= 1.0
KIE = kM
/ kH = 4.5 x 107 / 8 x 107 = 0.6
kH
= 8 x 107 dm3mol-1s-1
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm
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