Organic Solutes in Aqueous Solutions

B38

B40

Ethylene

      Jean, Y.C., Ganti, Cheng, K.L., Venkateswaran, K. and Walker, D.C.
Hyperfine Interact., 1986, 32, 813.

Reaction: H2C = CH2 + Mu ® MuH2C-CH2

Type of reaction: addition to olefinic bond

kM = 1.4 x 1010 dm3mol-1s-1   

KIE = kM / kH = 1.4 x 1010 / 3 x 109 = 5

kH = 3 x 109 dm3mol-1s-1  from: www.rcdc.nd.edu/compilations/HAtom/H.htm

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