C10
C11
Water – H2O
Reaction: H2O + Mu
®
H + MuHO no
reaction
H2O + Mu ®
MuH + OH
detected
Type of reaction: atom exchange
and/or abstraction
Nagamine, K., Nishiyama, K.,
Imazato, I., Nakayama, H., Yoshida, M., Sakai, Y., Sato, H. and Tominaya, T.
Chem. Phys. Lett., 1982, 87, 186.
kM < 9 x 102
dm3mol-1s-1
kH
»
1 x 101dm3mol-1s-1 at pH = 10 – 13
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm
value too low to measure
reliably
KIE not available
High temperature reaction
Percival, P.W., Brodovitch, J-C.,
Ghandi, K., Addison-Jones, B., Schutch, J. and Bartels, M. Phys. Chem. Chem.
Phys. 1999, 1, 4999.
kM < 2 x 104
dm3mol-1s-1 (upper limit at 400 ° C)
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