C15
Barnabas,
M.V. and Walker, D.C.
Can.
J. Chem., 1991,
69, 1252.
Reaction:
CH3COOH + Mu
®CH2COOH + MuH
Type
of reaction: abstraction (proposed)
kM
< 105dm3mol-1s-1
KIE = KM
/ kH < 105 / 1.0 x 105 < 1
kH
= 1.0 x 105 dm3mol-1s-1 at pH = 7
– 8 average of 2 values
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm
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