C1
Venkatesvaran,
K., Barnabas, M.V., Ng, B.W. and Walker, D.C.
Can.
J. Chem., 1988,
66, 1979.
Reaction:
Br-
+ Mu ↔
Mu Br-
Type
of reaction:
addition (as proposed for H atom reaction)
kM
< 106dm3mol-1s-1
KIE = kM
/ kH < 106 / 1.7 x 106 < 0.6
kH
= (1.7 ±
0.3) x 106dm3mol-1s-1
Ea
»
0 (6.3 ±
6.2) kJ/mol-1 for T = 283 K to 331 K
from:
Bartels, D.M. and Mezyk, S.P. J. Phys. Chem., 1993, 97, 4101.
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