Organic Solutes in Aqueous Solutions

B57

B58

Naphthalene

Ng, B.W., Stadlbauer, J.M. and Walker, D.C.

J. Chem. Phys., 1981, 75, 2879.

Reaction: C10H8 + Mu ® MuC10H8

Type of reaction: addition to aromatic ring

kM = (1.3 ± 0.3) x 109 dm3mol-1s-1   

KIE = kM / kH = 1.3 x 109 / 3.4 x 109 = 0.4

kH = 3.4 x 109 dm3mol-1s-1  from: www.rcdc.nd.edu/compilations/HAtom/H.htm 
 

Muonium reactions in the micellar systems

kM = (0.8 ± 0.5) x 109 dm3mol-1s-1 in NaLS micelles

from: Jean, Y.C., Ng, B.W., Stadlbauer, I.M. and Walker, D.C., J. Chem. Phys., 1981, 75,

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