B66
Barnabas,
M.V. and Walker, D.C.
Can.
J. Chem., 1991,
69, 1252.
Reaction:
HSC(CH2)CH(H)NH2C(=O)OH + Mu ®
MuH + ?
Type
of reaction: H – atom abstraction (proposed)
kM
= 4 x 109 dm3mol-1s-1
KIE = kM
/ kH = 4 x 109 / 2.3 x 109 »
1.6
kH
= 2.3 x 109 dm3mol-1s-1 at pH
= 6.0 from:
www.rcdc.nd.edu/compilations/HAtom/H.htm
Muonium reactions in the micellar systems
kM = 4 x 109 dm3mol-1s-1
in the CTAB micelles
from: Barnabas, M.V. and Walker, D.C., Can. J. Chem.
1999, 69, 1252.
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