B67
3-Pentanone
(diethyl
ketone)
Stadlbauer,
J.M., Venkatesvaran, K. and Walker, D.C.
Can.
J. Chem., 1997,
75, 74.
Reaction: CH3C(=O)C2H5
+ Mu ®
CH3C(OMu)C2H5
Type
of reaction: addition to C=O bond
with Mu attached to O atom
kM
= (8.4 ±
1.5) x 107 dm3mol-1s-1
at pH = 6-7
KIE = kM
/ kH = 8.4 x 107 / 4.2 x 107 = 2.0
kH
= (4.20 ±
0.15) x 107 dm3mol-1s-1
from:
Mezyk, S.P., Lossack, A. and Bartels, D.M. Can. J. Chem., 1997, 75,
1114.
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