Organic Solutes in Aqueous Solutions

B67

B67

Phenol

Jean, Y.C., Brewer, J.H., Fleming, D.G., Garner, D.M., Mikula, R.J., Vaz, L.C.

and Walker, D.C. Chem. Phys. Lett., 1978, 57, 293.

Reaction: C6H5OH + Mu ® MuC6H5OH

Type of reaction: addition to ring

kM = 7 x 109 dm3mol-1s-1  

KIE = kM / kH = 7 x 109 / 1.7 x 109 = 4

kH = 1.7 x 109 dm3mol-1s-1 at pH = 2 – 7 average of 3 values

from: www.rcdc.nd.edu/compilations/HAtom/H.htm
 

Muonium reactions in the micellar systems

kM = (1.4 ± 0.3) 109 dm3mol-1s-1 in the NaOSA micelles

from: Jean, Y.C., Ng, B.W., Stadlbauer, I.M. and Walker, D.C., J. Chem. Phys., 1981, 75, 2879


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