B79
Reaction:
C6H5CH=CH2 + Mu ®
C6H5CH-CH2Mu
C6H5CH=CH2
+ Mu ®
(Mu) C6H5CH=CH2
Type
of reaction: addition to side chain
(predominantly) and into benzene ring
a)
Venkateswaran, K., Barnabas, M.V., Wu, Z., Stadlbauer, J.M., Ng, B.W.
and Walker, D.C. Chem. Phys., 1989, 137, 239.
kM
= 2.0 x 1010 dm3mol-1s-1
b) Venkateswaran,
K., Barnabas, M.V., Stadlbauer, J.M. and Walker, D.C.
Can.
J. Chem. 1990, 68, 952.
kM
= 9 x 109 dm3mol-1s-1
KIEav
= kM / kH = 1.45 x 1010 / 5.7 x 109
= 2.5
kH
= 5.7 x 109 dm3mol-1s-1
for addition to side chain
from
www.rcdc.nd.edu/compilations/HAtom/H.htm
Muonium
reactions in the micellar systems
kM = 8 x 1010 dm3mol-1s-1
in the CTAB micelles
from: Venkateswaran, K., Barnabas, M.V., Stadlbauer, I.M.
and Walker, D.C. Can. J. Chem. 1990, 68, 952.
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