B80
TEMPO – 2,2,6,6-tetramethyl-1-piperidynyloxy (free radical)
Karolczak, S., Gillis, H.A., Porter, G.B. and Walker, D.C.
Can. J. Chem., 2003, 81, 175
Reaction: TEMPO + Mu
® TEMPOMu
TEMPO + Mu
(↑↑
)
®
TEMPO + Mu(↑↓)
Type of reaction: combination and (?) spin exchange
kM
= (1.6 ±
0.3) x 1010 dm3mol-1s-1
KIE= 3.7
± 1.0
KH= 4.9 x 109
dm3mol-1s-1
From :www.rcdc.nd/compilation/Hatom/H.HTM
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