B81
TEMPO–OH-2,2,6,6-tetramethyl-4-hydroxy-1-piperidinyloxy (free radical)
Karolczak, S., Gillis, H.A., Porter, G.B. and Walker, D.C.
Can. J. Chem., 2003, 81, 175
Reaction: TEMPO-OH + Mu
®
TEMPO-Mu
TEMPO-OH + Mu
()
®
TEMPO + Mu(↑↓)
Type of reaction: combination and
(?) spin exchange
kM
= (1.4 ±
0.3) x 1010 dm3mol-1s-1
kH
unknown
KIE - anavailable