Organic Solutes in Aqueous Solutions

B80

B81

TEMPO–OH-2,2,6,6-tetramethyl-4-hydroxy-1-piperidinyloxy (free radical)
 

Karolczak, S., Gillis, H.A., Porter, G.B. and Walker, D.C.
Can. J. Chem., 2003, 81, 175

Reaction:          TEMPO-OH + Mu ® TEMPO-Mu

                        TEMPO-OH + Mu (­­) ® TEMPO + Mu(↑↓)

Type of reaction: combination and (?) spin exchange

kM = (1.4 ± 0.3) x 1010 dm3mol-1s-1

kH  unknown

KIE - anavailable

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