B82
Reaction:
[(CH3)2N]2C=S + Mu ®
[(CH3)2N]2CSMu
Type
of reaction: addition to C=S bond with Mu added to S atom
Barnabas,
M.V., Venkateswaran, K. and Walker, D.C.
Can.
J. Chem., 1989,
67, 120.
kM
= 4 x 1010 dm3mol-1s-1
pH = 7.0
Barnabas,
M.V. and Walker, D.C.
Can.
J. Chem., 1991,
69, 1252.
kM
= 3 x 109 dm3mol-1s-1
pH = 1.0
kH
– unknown
KIE
- unavailable
Muonium
reactions in the micellar systems
kM = 2 x 1010 dm3mol-1s-1
in the CTAB micelles
from: Barnabas, M.V. and Walker, D.C., Can. J. Chem.
1999, 69, 1252.