Organic Solutes in Aqueous Solutions

B78

B82

Tetramethylthiourea

Reaction: [(CH3)2N]2C=S + Mu ® [(CH3)2N]2CSMu

Type of reaction: addition to C=S bond with Mu added to S atom

Barnabas, M.V., Venkateswaran, K. and Walker, D.C.
Can. J. Chem., 1989, 67, 120.

kM = 4 x 1010 dm3mol-1s-1    pH = 7.0

Barnabas, M.V. and Walker, D.C.

Can. J. Chem., 1991, 69, 1252.

kM = 3 x 109 dm3mol-1s-1  pH = 1.0

kH – unknown

KIE - unavailable

 

Muonium reactions in the micellar systems

kM = 2 x 1010 dm3mol-1s-1 in the CTAB micelles

from: Barnabas, M.V. and Walker, D.C., Can. J. Chem. 1999, 69, 1252.


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