B86
Reaction:
Thymine + Mu ®
Mu + Thymine adduct
Type
of reaction: addition to C(5) and C(6)
Barnabas,
M.V., Venkateswaran, K. and Walker, D.C.
Can.
J. Chem., 1989,
67, 120.
kM
= 3 x 109 dm3mol-1s-1
KIE = kM
/ kH = 3 x 109 / 5.7 x 108 = 5.3
kH
= 5.7 x 108 dm3mol-1s-1
average of 2 values
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm
a)
Bucci, S., Crippa, P.R., de Munari, G.M., Guidi, G., Manfredi, M., Tedeschi,
R., Vecli, A. and Podini, P. Hyperfine Interaction, 1979, 6,
425. b) Bucci, C. in Muons and
Pions in Material Research, ed. J. Chappert and R.T. Gryszpan, Elsevier
Science Publisher B.V. 1984.
kM
= [(8 ±
1) ¸
(9.5 ±
1.0)] x 109 dm3mol-1s-1
rate
constant dependent on the magnetic field applied
KIE = kM
/ kH = 8.7 x 109 / 5.7 x 108 »
15
kH
= 5.7 x 108 dm3mol-1s-1
average of 2 values
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm
Muonium reactions in the micellar systems
kM = 3 x 109 dm3mol-1s-1
in the CTAB micelles
from: Barnabas, M.V. and Walker, D.C., Can. J. Chem.
1999, 69, 1252.
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