B87
Thymine
5-monophosphate (T5MP)
a)
Bucci, S., Crippa, P.R., de Munari, G.M., Guidi, G., Manfredi, M., Tedeschi,
R., Vecli, A. and Podini, P. Hyperfine Interaction, 1979, 6,
425. b) Bucci, C. in Muons and
Pions in Material Research, ed. J. Chappert and R.T. Gryszpan, Elsevier
Science Publisher B.V. 1984.
Reaction:
Thymine-5-monophosphate + Mu ®
MuT5MP
Type
of reaction: addition to C(5) and C(6) in the ring
kM
= (7 ±
1) x 109 m3mol-1s-1
average of 2 values
kH
= 2.3 x 108 dm3mol-1s-1
from: Bucci, Et al., ibid.
KIE = kM
/ kH = 7 x 109 / 2.3 x 108 = 30