Organic Solutes in Aqueous Solutions

B83

B87

Thymine 5-monophosphate (T5MP)

a) Bucci, S., Crippa, P.R., de Munari, G.M., Guidi, G., Manfredi, M., Tedeschi, R., Vecli, A. and Podini, P. Hyperfine Interaction, 1979, 6, 425. b) Bucci, C. in  Muons and Pions in Material Research, ed. J. Chappert and R.T. Gryszpan, Elsevier Science Publisher B.V. 1984.

Reaction: Thymine-5-monophosphate + Mu ® MuT5MP

Type of reaction: addition to C(5) and C(6) in the ring

kM = (7 ± 1) x 109 m3mol-1s-1    average of 2 values

kH = 2.3 x 108 dm3mol-1s-1   from:  Bucci, Et al., ibid.

KIE = kM / kH = 7 x 109 / 2.3 x 108 = 30

 

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