Percival,
P.W., Roduner, E. and Fischer, H.
in Adv.
Chem. Ser. 1979, 175, 335; ed. by H.J. Ache, ACS, Washington DC,
1979.
Reaction:
CH3CH2CH(OH)CH3 + Mu
® MuH + CH3CH2
C(OH) CH3
Type of
reaction: abstraction (proposed by analogy to H atom reaction)
kM = 1.1 x 106dm3mol-1s-1
KIE = kM / kH = 1.1 x 106 /
1 x 108 ~ 0.01
kH
= 1.0 x 108dm3mol-1s-1 average of 2 values
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm
Print
Next