B24
Butanone
(methylethyl ketone)
Stadlbauer, J.M., Venkatesvaran, K. and Walker, D.C.
Can. J. Chem.,
1997, 75, 74.
Reaction: CH3COCH2CH3
+ Mu
®
CH3CO(Mu)CH2CH3
Type of reaction: addition to C = O bond with Mu attached
to O atom
kM
= (9.9 ±
1.0) x 107 dm3mol-1s-1
KIE = kM
/ kH = 9.4 x 107 / 2.20 x 107
= 4.3
kH = (2.20
±
0.32) x 107 dm3mol-1s-1
from :www.rcdc.nd.edu/compilations/Hatom/HTM
Print
Next