Organic Solutes in Aqueous Solutions

B25 Chloroacetate ion Stadlbauer, J.M., Venkateswaran, K. and Walker, D.C. Radiat. Phys. Chem., 1997, 50, 259. Reaction:            ClCH2COO- + Mu ® HMu + ClCHCOO-                           ClCH2COO- + Mu ® Cl- + m+ + CH2COO- Type of reaction: H atom abstraction and “dechlorination” (atom addition or electron transfer, followed by dissociation) kM = 9.1 x 105 dm3mol-1s-1  at pH = 5.5  (99.8 %  of anion form)  KIE = kM / kH = 9.1 x 105 / 2.4 x 106 ~ 0.4 kH = 2.4 x 106 dm3mol-1s-1    at pH ~ 7 from: www.rcdc.nd.edu/compilations/HAtom/H.htm

Print

Next

Table A - Inorganic Solutes in Aqueous Solutions
Table B - Organic Solutes in Aqueous Solutions
Table C - Solutes Unreactive Towards Muonium Atoms in Aqueous Solutions
Table D - Inorganic and Organic Solutes in Nonaqueous Solutions
Table E - Early Muonium Rate Constants
Table F - (P_M) and (P_D) fractions

Back to the top