B38
Percival,
P.W., Roduner, E. and Fischer, H.
in
Adv. Chem. Ser. 1979, 175, 335; ed. by H.J. Ache, ACS,
Washington DC, 1979.
Reaction:
CH3CH2OH + Mu ®
MuH + C2H4OH (C2H4OH mainly CH3CHOH)
Type
of reaction: abstraction (proposed by analogy to H atom reaction)
kM
£
3 x 105dm3mol-1s-1
kM derived from
l0 in the pure alcohol assuming "concentration
" of pure alcohol of 17.1M
KIE = kM
/ kH £
3 x 105 / 1.8 x 107 < 0.015
kH
= (1.8 ±
0.06) x 107dm3mol-1s-1
from:
Mezyk, S.P. and Bartels, D.M. J.
Phys. Chem., 1997, 101, 1329
-latest entry in www.rcdc.nd.edu/compilation/Hatom/H.HTM
value recommended in RCDC: kH
= 1.7 x 107dm3mol-1s-1
.
Print
Next