Organic Solutes in Aqueous Solutions

B37

B39

Ethylacetate

Venkateswaran, K., Barnabas, M.V., Stadlbauer, J.M. and Walker, D.C.

Can. J. Chem., 1990¸68, 952.

Reaction: CH3COOC2H5 + Mu ® MuH + ?

Type of reaction: H abstraction

kM = 1.5 x 107 dm3mol-1s-1   

KIE = kM / kH = 1.5 x 107 / 2.5 x 105 = 60

kH = 2.5 x 105 dm3mol-1s-1  from: www.rcdc.nd.edu/compilations/HAtom/H.htm
 

Muonium reactions in the micellar systems

kM = 1.8 x 1010 dm3mol-1s-1 in the CTAB (?) micelles

from: Venkateswaran, K., Barnabas, M.V., Stadlbauer, I.M. and Walker, D.C. Can. J. Chem. 1990, 68, 952.


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