B3
Acetonitrile
Stadlbauer,
J.M., Ng, B.W., Jean, Y.C. and Walker, D.C.
J.
Phys. Chem., 1983,
87, 841.
Reaction:
CH3CN
+ Mu ®
CH3MuCN
?
Type
of reaction: addition to CN
bond
kM
= 5.1 x 107 dm3mol-1s-1
KIE
= kM / kH = 5.1 x 107 / 2.5 x 106
= 20
kH
= 2.5 x 106 dm3mol-1s-1 average of
3 values from:
www.rcdc.nd.edu/compilations/HAtom/H.htm
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