Organic Solutes in Aqueous Solutions

B4

B4

Acrylamide

Stadlbauer, J.M. , Ng, B.W.,  Walker, D.C., Jean, Y.C. and Ito, Y.
Can. J. Chem., 1981, 59, 3261.

Reaction: CH2=CHCONH2 + Mu ® MuCH2CHCONH2

Type of reaction: addition across the olefinic bond

kM = (1.90 ± 0.13) x 1010 dm3mol-1s-1 

KIE = kM / kH = 1.9 x 1010 / 7.5 x 109 = 2.5

most recent data kH = (7.5 ± 1.0) 109dm3mol-1s-1

from: Vojnarowits, L., at all (to be published)


 

Muonium reactions in the micellar systems

kM » 2 x 1010 dm3mol-1s-1 in the CTAB micelles

from: Barnabas, M.V. and Walker, D.C., Can. J. Chem. 1999, 69, 1252.

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