B4
B4
Stadlbauer,
J.M. , Ng, B.W., Walker, D.C.,
Jean, Y.C. and Ito, Y.
Can.
J. Chem., 1981, 59,
3261.
Reaction:
CH2=CHCONH2 + Mu ®
MuCH2CHCONH2
Type
of reaction: addition across the olefinic bond
kM
= (1.90 ±
0.13) x 1010 dm3mol-1s-1
KIE = kM
/ kH = 1.9 x 1010 / 7.5 x 109 = 2.5
most
recent data kH = (7.5 ± 1.0)
109dm3mol-1s-1
from: Vojnarowits, L.,
at all (to be published)
Muonium reactions in the micellar systems
kM
»
2 x 1010 dm3mol-1s-1
in the CTAB micelles
from: Barnabas, M.V. and Walker, D.C., Can. J. Chem.
1999, 69, 1252.
|