Organic Solutes in Aqueous Solutions

B5

B5

Acrylic acid

Stadlbauer, J.M. , Ng, B.W.,  Walker, D.C., Jean, Y.C. and Ito, Y.
Can. J. Chem., 1981, 59, 3261.

Reaction: CH2 = CHCOOH + Mu ® MuCH2-CHCOOH

Type of reaction: addition across the double bond

kM = (1.55 ± 0.25) x 1010 dm3mol-1s-1   

kM
for unbuffered solution with appr. 64% solute dissociated

KIE = kM / kH = 1.55 x 1010 / 3.3 x 109 = 4.7

kH = 3.3 x 109 dm3mol-1s-1  from: www.rcdc.nd.edu/compilations/HAtom/H.htm

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