B5
Stadlbauer,
J.M. , Ng, B.W., Walker, D.C.,
Jean, Y.C. and Ito, Y.
Can.
J. Chem., 1981, 59,
3261.
Reaction:
CH2 = CHCOOH + Mu ®
MuCH2-CHCOOH
Type
of reaction: addition across the double bond
kM
= (1.55 ±
0.25) x 1010 dm3mol-1s-1
kM
for unbuffered solution with appr.
64% solute dissociated
KIE
= kM / kH = 1.55 x 1010 / 3.3 x 109
= 4.7
kH
= 3.3 x 109 dm3mol-1s-1
from: www.rcdc.nd.edu/compilations/HAtom/H.htm