Organic Solutes in Aqueous Solutions

B6

B6

Acrylonitrile

Stadlbauer, J.M. , Ng, B.W.,  Walker, D.C., Jean, Y.C. and Ito, Y.
Can. J. Chem., 1981, 59, 3261.

Reaction: CH2 = CHCN + Mu ® MuCH2-CHCN

Type of reaction: addition across the double bond

kM = (1.14 ± 0.2) x 1010 dm3mol-1s-1   

KIE = kM / kH = 1.14 x 1010 / 3.0 x 109 = 3.8

kH = 3.0 x 109 dm3mol-1s-1  average of 2 values

from: www.rcdc.nd.edu/compilations/HAtom/H.htm

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