B6
Stadlbauer,
J.M. , Ng, B.W., Walker, D.C.,
Jean, Y.C. and Ito, Y.
Can.
J. Chem., 1981, 59,
3261.
Reaction:
CH2 = CHCN + Mu ®
MuCH2-CHCN
Type
of reaction: addition across the double bond
kM
= (1.14 ±
0.2) x 1010 dm3mol-1s-1
KIE
= kM / kH = 1.14 x 1010 / 3.0 x 109
= 3.8
kH
= 3.0 x 109 dm3mol-1s-1
average of 2 values
from: www.rcdc.nd.edu/compilations/HAtom/H.htm