B13
Percival,
P.W., Roduner, E. and Fischer, H.
in
Adv. Chem. Ser. 1979, 175, 335; ed. by H.J. Ache, ACS,
Washington DC, 1979.
Reaction:
Ascorbic acid + Mu ®
Mu adduct
Type
of reaction: addition
kM
= 1.8 x 109 dm3mol-1s-1
pH = 1.0
KIE = kM
/ kH = 1.8 x 109 / 1.3 x 108 = 14
kH
= 1.3 x 108 dm3mol-1s-1
average of 2 values
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm