B14
Reaction:
C6H6 + Mu ®
C6H6Mu
Type
of reaction: addition to the ring – formation of Mu substituted
cyclohexadienyl radical
a)
Roduner,
E., Louwrier, P.W.F., Brinkman, G.A., Garnet, D.M., Reid, I.D., Arseneau, D.J.,
Senba, M. and Fleming, D.G. Ber. Bunsenges.
Phys. Chem., 1990, 94,
1224.
kM
= (1.9 ±0.4)
x 109 dm3mol-1s-1
log(A/dm3mol-1s-1)
= 9.99 Ea = 6.7
kJ mol-1
KIE = kM
/ kH = 1.9 x 109 / 1.1 x 109 = 1.7
b)
Stadlbauer, J.M., Ng, B.W., Ganti, R. and Walker, D.C.
J. Am. Chem. Soc., 1984, 106, 3151.
kM
= 3.3 x 109 dm3mol-1s-1
KIE = kM
/ kH = 3.3 x 109 / 1.1 x 109 = 3.0
kH
= (1.1 ±
0.1) x 109 dm3mol-1s-1
log(A/dm3mol-1s-1)
= 12.34 ±
0.09 Ea = (19.1 ±
0.6) kJ mol-1 for: T = 279 K to 367 K
from:
Roduner, E. and Bartels, D.M. Ber. Bunsenges.
Phys. Chem., 1992, 96,
1037.
Muonium reactions at high
temperatures and pressures
Ghandi,K., Addison-Jones,B.,
Brodovitch, McKenzie,I., Kecman,S. and Percival,P.W.
Physica B ,2003, 326,55
|
T/°C |
P/bar |
kMu/1010 M-1s-1 |
|
171 |
328 |
0.33(12) |
|
205 |
225 |
0.36(12) |
|
231 |
225 |
0.43(14) |
|
257 |
360 |
0.54(14) |
|
310 |
400 |
0.54(15) |
|
330 |
350 |
0.66(16) |
|
121 |
250 |
0.54(8) |
|
152 |
250 |
0.67(8) |
|
205 |
250 |
0.68(9) |
|
231 |
398 |
0.73(9) |
|
310 |
315 |
0.56(9) |
|
284 |
252 |
0.56(9) |
|
284 |
380 |
0.56(9) |
|
284 |
203 |
0.60(9) |
|
257 |
250 |
0.68(9) |
|
362 |
255 |
0.22(9) |
|
179 |
250 |
0.52(9) |
|
179 |
250 |
0.45(9) |
|
90 |
14 |
0.32(7) |
|
383 |
315 |
0.23(7) |
|
394 |
320 |
0.11(7) |
|
373 |
320 |
0.33(6) |
|
373 |
250 |
0.13(7) |
|
352 |
250 |
0.37(6) |
|
352 |
250 |
0.35(6) |
|
341 |
250 |
0.43(6) |
|
331 |
250 |
0.46(6) |
|
373 |
396 |
0.39(6) |
|
373 |
380 |
0.19(6) |
|
310 |
200 |
0.48(7) |
|
310 |
246 |
0.53(7) |
|
257 |
290 |
0.72(8) |
|
205 |
250 |
0.62(8) |
|
152 |
246 |
0.62(8) |
|
112 |
255 |
0.46(7) |
|
121 |
5 |
0.27(5) |
|
147 |
9 |
0.70(21) |
|
171 |
18 |
0.79(11) |
|
257 |
85 |
0.61(7) |
|
6.5 |
1 |
0.13(2) |
|
25 |
1 |
0.16(3) |
|
25 |
1 |
0.19(3) |
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