Organic Solutes in Aqueous Solutions

B15

B15

Benzaldehyde

Stadlbauer, J.M., Ng, B.W., Ganti, R. and Walker, D.C.

J. Am. Chem. Soc., 1984, 106, 3151.

Reaction: C6H5CHO + Mu ® MuC6H5CHO

Type of reaction: addition to benzene ring

kM = 5.1 x 109 dm3mol-1s-1    

KIE = kM / kH = 5.1 x 109 / 1.4 x 109 = 3.6

kH = 1.4 x 109 dm3mol-1s-1  from: www.rcdc.nd.edu/compilations/HAtom/H.htm

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