Organic Solutes in Aqueous Solutions

B16 Benzoic acid Reaction: C6H5COOH + Mu ® MuC6H5COOH Type of reaction: addition into benzene ring with Mu in ortho, meta, para position to COOH solution          Venkateswaran, K., Stadlbauer, J.M., Wu, Z., Gillis, H.A. and Walker, D.C.   J. Phys. Chem., 1996, 100, 3569. kMu = (2.5 ± 0.5) x 1010 dm3mol-1s-1                          pH = 1- 2 kMu = (8 ± 3) x 109 dm3mol-1s-1                                 pH ~ 7 (natural) kMu = (8 ± 3) x 109 dm3mol-1s-1                                 pH ~ 10 KIE = kM / kH = 2.5 x 1010 / 9.2 x 108 = 27                 pH = 1-2 KIE = kM / kH = 8 x 109 / 9.2 x 108 = 8.7                    pH ~ 7 kH = 9.2 x 108 dm3mol-1s-1  at  pH = 3 selected value from: www.rcdc.nd.edu.edu/compilations/Hatom/H.HTM

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Table A - Inorganic Solutes in Aqueous Solutions
Table B - Organic Solutes in Aqueous Solutions
Table C - Solutes Unreactive Towards Muonium Atoms in Aqueous Solutions
Table D - Inorganic and Organic Solutes in Nonaqueous Solutions
Table E - Early Muonium Rate Constants
Table F - (P_M) and (P_D) fractions

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