B17
Benzonitrile
(cyanobenzene)
Stadlbauer,
J.M., Ng, B.W., Ganti, R. and Walker, D.C.
J.
Am. Chem. Soc., 1984,
106, 3151.
Reaction:
C6H5CN + Mu ®
MuC6H5CN
Type
of reaction: addition to benzene ring
kM
= 7.2 x 109 dm3mol-1s-1
KIE = kM
/ kH = 7.2 x 109 / 6.8 x 108 = 10.5
kH
= 6.8 x 108 dm3mol-1s-1
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm