B18
Barnabas,
M.V. and Walker, D.C.
Can.
J. Chem., 1991,
69, 1252.
Reaction: (C6H5)2C
= O + Mu ®
MuC6H5C(=O)C6H5
Type
of reaction: addition to benzene ring
kM
= 2 x 1010 dm3mol-1s-1
KIE = kM
/ kH = 2 x 1010 / 6.1 x 109 »
3
kH
= 6.1 x 109 dm3mol-1s-1 average
from two values 6.6 x 109 and 5.6 x 109 dm3mol-1s-1
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm
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