Organic Solutes in Aqueous Solutions

B19

B19

1,4-Benzoquinone

Barnabas, M.V., Venkateswaran, K. and Walker, D.C.

Can. J. Chem., 1989, 67, 120.

Reaction: C6H4O2 + Mu ® ?

Type of reaction: addition into benzene ring and C=O bond (?)

kM = 2.5 x 1010 dm3mol-1s-1

KIE = kM / kH = 2.5 x 1010 / 8.3 x 109 = 3.0

kH = 8.3 x 109 dm3mol-1s-1

from: www.rcdc.nd.edu/compilations/HAtom/H.htm
 

Muonium reactions in the micellar systems

kM = 2.5 x 1010 dm3mol-1s-1 in the CTAB micelles

from: Barnabas, M.V. and Walker, D.C., Can. J. Chem. 1999, 69, 1252.


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