B20
Percival,
P.W., Roduner, E. and Fischer, H.
in
Adv. Chem. Ser. 1979, 175, 335; ed. by H.J. Ache, ACS,
Washington DC, 1979.
Reaction:
BrCH2COOH + Mu ®
MuBr + CH2COOH
Type
of reaction: bromine abstraction
kM
= 1.5 x 109 dm3mol-1s-1
at pH = 1.0
KIE = kM
/ kH = 1.5 x 109 / 3.3 x 108 = 4.5
kH
= 3.3 x 108 dm3mol-1s-1
pH = 1.0 average of 3
values
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm
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