Organic Solutes in Aqueous Solutions

B30 Cyclohexanone Stadlbauer, J.M., Venkatesvaran, K. and Walker, D.C. Can. J. Chem., 1997, 75, 74. Reaction: C-(CH2)5C=O + Mu ® C-(CH2)5COMu Type of reaction: addition to C=O  bond with Mu attached to O atom kM = (1.17 ± 0.2) x 108 dm3mol-1s-1    at pH = 6-7 kH – unknown for cyclohexanone but determined for cyclopentanone: kH = (4.91 ± 0.28) x 107 dm3mol-1s-1 Mezyk, S.P., Lossack, A. and Bartels, D.M. Can. J. Chem., 1997, 75, 1114. assuming similar values of kH for cyclopentanone and cyclohexanone one obtains KIE = kM / kH = 1.2 x 108 / 4.9 x 107 » 2.5

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Table A - Inorganic Solutes in Aqueous Solutions
Table B - Organic Solutes in Aqueous Solutions
Table C - Solutes Unreactive Towards Muonium Atoms in Aqueous Solutions
Table D - Inorganic and Organic Solutes in Nonaqueous Solutions
Table E - Early Muonium Rate Constants
Table F - (P_M) and (P_D) fractions

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