Organic Solutes in Aqueous Solutions

B30

B31

Cytosine

Barnabas, M.V., Venkateswaran, K. and Walker, D.C.

Can. J. Chem., 1989, 67, 120.

Reaction: Cytosine + Mu ® Mu cytosine adduct

Type of reaction: addition to C(5) and C(6)

kMu = 3 x 109 dm3mol-1s-1   

KIE = kM / kH = 3 x 109 / 9.2 x 107 » 30

kH = 9.2 x 107 dm3mol-1s-1  at pH = 7  from: www.rcdc.nd.edu/compilations/HAtom/H.htm

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