Organic Solutes in Aqueous Solutions

B31

B32

Cytosine 5-monophosphate (C5MP)

a) Bucci, S., Crippa, P.R., de Munari, G.M., Guidi, G., Manfredi, M., Tedeschi, R., Vecli, A. and Podini, P. Hyperfine Interaction, 1979, 6, 425. b) Bucci, C. in  Muons and Pions in Material Research, ed. J. Chappert and R.T. Gryszpan, Elsevier Science Publisher B.V. 1984.

Reaction: C5MP + Mu ® Mu-C5MP adduct

Type of reaction: addition to C(5) and C(6) by analogy to Mu reaction with cytosine

kM = (4.8 ± 0.5) x 109 dm3mol-1s-1   

 

KIE = kM / kH = 4.8 x 109 / 9 x 107 = 53

kH = 9 x 107 dm3mol-1s-1  from: Bucci, et al., ibid.

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