B33
Barnabas,
M.V. and Walker, D.C.
Can.
J. Chem., 1991,
69, 1252.
Reaction:
HS-CH2CHNH2COOH
+ Mu ®
MuH + ?
or
HS-CH2CH(NH3+)COOH
+ Mu ®
MuH + ?
Type
of reaction: H – atom abstraction (proposed)
kM
= 6 x 109 dm3mol-1s-1
KIE = kM
/ kH = 6 x 109 / 1.8 x 109 = 3.3
kH
= 1.8 x 1010 dm3mol-1s-1
at pH = 6.0
for conjugated acid
from:
www.rcdc.nd.edu/compilations/HAtom/H.htm