Organic Solutes in Aqueous Solutions

B36

B37

Dimethylthioformamide (DMTF)

Barnabas, M.V. and Walker, D.C.

Can. J. Chem., 1991, 69, 1252.

Reaction: HC(=S)N(CH3)2 + Mu ® HC(-S)(Mu)N(CH3)2

Type of reaction: addition to C=S with Mu attached to C atom

kM = 7 x 1010 dm3mol-1s-1   

kH – unknown

KIE – not available

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